{"id":966,"date":"2019-07-26T16:21:01","date_gmt":"2019-07-26T20:21:01","guid":{"rendered":"https:\/\/carleton.ca\/barrylab\/?page_id=966"},"modified":"2025-01-22T13:36:43","modified_gmt":"2025-01-22T18:36:43","slug":"chem-3100","status":"publish","type":"page","link":"https:\/\/carleton.ca\/barrylab\/chem-3100\/","title":{"rendered":"Chem 2104"},"content":{"rendered":"<h2><strong>Syllabus<\/strong><\/h2>\n<p><span style=\"text-decoration: underline;\"><strong>Title<\/strong><\/span><\/p>\n<p><span class=\"courseblocktitle\">Physical Chemistry II<\/span><\/p>\n<p><span style=\"text-decoration: underline;\"><strong>Course Description<\/strong><\/span><\/p>\n<p>Further development of thermodynamic equations and their applications to mass changes, chemical potential, chemical equilibria, transport properties and advanced phase equilibria. Use of partial differentials and development of Maxwell&#8217;s relations will also be covered.<\/p>\n<p><strong><span style=\"text-decoration: underline;\">Prerequisite<\/span><\/strong><\/p>\n<p>CHEM 2103 or BIOC 2300<br \/>\nMATH 1005 or MATH 2007<\/p>\n<p><span style=\"text-decoration: underline;\"><strong>Grading Scheme<\/strong><\/span><\/p>\n<p>The laboratory is worth 30% of your final mark. The other 70% is from assignments and exams, as follows:<\/p>\n<p>Assignments 14%<br \/>\nIn-term exam 21%<br \/>\nFinal exam 35%<br \/>\nLaboratory 30%<\/p>\n<p><span style=\"text-decoration: underline;\"><strong>Lectures<\/strong><\/span><\/p>\n<p>Monday and Wednesday, 10:05 &#8211; 11:35 am, Loeb Building B146<\/p>\n<p><span style=\"text-decoration: underline;\"><strong>Tutorial<\/strong><\/span><\/p>\n<p>Friday 5:35\u00a0 \u2013 6:35 pm, Loeb Building B146 (run by <a href=\"https:\/\/carleton.ca\/barrylab\/people\/juliana-dimova\/\">Dex<\/a>)<\/p>\n<p><strong><span style=\"text-decoration: underline;\">Laboratory<\/span><\/strong><\/p>\n<p>The lab is run by Daniel Sun, and he has an extensive website about it on Brightspace.<\/p>\n<p><span style=\"text-decoration: underline;\"><strong>Exams<\/strong><\/span><\/p>\n<p>This is the <a href=\"https:\/\/carleton.ca\/barrylab\/wp-content\/uploads\/eq-sheet.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">equation sheet<\/a> provided on all exams.<\/p>\n<p><strong>In-term Exam<\/strong>: March 12, 10:05 &#8211; 11:35 am, Loeb B146 (Dex to proctor)<br \/>\n<strong>Final Exam<\/strong>: TBA<\/p>\n<p><b><u>Text<\/u><\/b><\/p>\n<p>You do not have to buy a textbook but you will need a secondary source. I recommend: Engel and Reid <em>Physical Chemistry.<\/em> New, it costs ~$225 on Amazon, but a second-hand copy is a better idea.<\/p>\n<p><b><u>Topics<\/u><\/b><\/p>\n<p><strong>Chemical Kinetics <\/strong><\/p>\n<ul>\n<li>Instantaneous rate, initial rate<\/li>\n<li>Reaction mechanisms<\/li>\n<li>Integrated rate laws<\/li>\n<li>Sequential and parallel reactions<\/li>\n<li>The Arrhenius equation and activation energy<\/li>\n<li>Equilibrium reactions<\/li>\n<li>Reaction mechanisms<\/li>\n<li>Catalysis<\/li>\n<\/ul>\n<p><strong>Phase Diagrams and Phase Changes<\/strong><\/p>\n<ul>\n<li>Phase diagrams<\/li>\n<li>Phase changes<\/li>\n<li>The phase rule<\/li>\n<li>Stabilities of the phases<\/li>\n<li>Phase diagrams and the phase rule<\/li>\n<li>The Clausius-Clapeyron equation<\/li>\n<li>Vapour pressure dependence on applied pressure<\/li>\n<li>Two-component phase diagrams<\/li>\n<\/ul>\n<p><strong>Chemical Potential and Solutions<\/strong><\/p>\n<ul>\n<li>Ideal solutions<\/li>\n<li>Chemical potential in gas and liquid phases<\/li>\n<li>Ideal binary solutions<\/li>\n<li>T-x diagrams and distillation<\/li>\n<li>Gibbs-Duhem equation<\/li>\n<li>Colligative properties<\/li>\n<li>Real solutions<\/li>\n<li>Activity coefficients<\/li>\n<li>Henry\u2019s Law, Raoult\u2019s Law in dilute solutions<\/li>\n<\/ul>\n<p><strong>Spectroscopy<\/strong><\/p>\n<ul>\n<li>General features of spectroscopy<\/li>\n<li>Rotational spectroscopy<\/li>\n<li>Diatomic vibrational spectroscopy<\/li>\n<li>Polyatomic vibrational spectroscopy<\/li>\n<\/ul>\n<p><strong><span style=\"text-decoration: underline;\">Survivors of Sexual Violence<\/span><br \/>\n<\/strong>As a community, Carleton University is committed to maintaining a positive learning, working and living environment where sexual violence will not be tolerated and is survivors are supported through academic accommodations as per Carleton&#8217;s Sexual Violence Policy. For more information about the services available at the university and to obtain information about sexual violence and\/or support, visit: <a href=\"http:\/\/carleton.ca\/sexual-violence-support\" target=\"_blank\" rel=\"noopener noreferrer\">carleton.ca\/sexual-violence-support<\/a><\/p>\n<p><strong><span style=\"text-decoration: underline;\">Requests for Academic Accommodation<\/span><br \/>\n<\/strong>You may need special arrangements to meet your academic obligations during the term. Please contact your instructor with any requests for academic accommodation (pregnancy, religion, disability, etc.) during the first two weeks of class, or as soon as possible after the need for accommodation is known to exist.<\/p>\n<p>For an accommodation request, the processes can be found here:<br \/>\n<a href=\"http:\/\/carleton.ca\/equity\/wp-content\/uploads\/Student-Guide-to-Academic-Accommodation.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">carleton.ca\/equity\/wp-content\/uploads\/Student-Guide-to-Academic-Accommodation.pdf<\/a><\/p>\n<p style=\"padding-left: 30px;\"><strong>Academic Accommodations for Students with Disabilities<br \/>\n<\/strong>If you have a documented disability requiring academic accommodations in this course, please contact the Paul Menton Centre for Students with Disabilities (PMC) at 613-520-6608 or <a href=\"&#109;&#x61;&#x69;l&#116;&#x6f;&#x3a;p&#109;&#x63;&#64;&#99;&#x61;&#x72;l&#101;&#x74;o&#110;&#x2e;&#x63;a\">p&#109;&#x63;&#x40;c&#97;&#114;&#x6c;&#x65;t&#111;&#x6e;&#x2e;c&#97;<\/a> for a formal evaluation or contact your PMC coordinator to send your instructor your Letter of Accommodation at the beginning of the term. You must also contact the PMC no later than two weeks before the first in-class scheduled test or exam requiring accommodation (if applicable). After requesting an accommodation from PMC, meet with your instructor as soon as possible to ensure accommodation arrangements are made. <a href=\"http:\/\/carleton.ca\/pmc\" target=\"_blank\" rel=\"noopener noreferrer\">carleton.ca\/pmc<\/a><\/p>\n<p style=\"padding-left: 30px;\"><strong>Accommodation for Student Activities<br \/>\n<\/strong>Carleton University recognizes the substantial benefits, both to the individual student and for the university, that result from a student participating in activities beyond the classroom experience. Reasonable accommodation must be provided to students who compete or perform at the national or international level. Please contact your instructor with any requests for academic accommodation during the first two weeks of class, or as soon as possible after the need for accommodation is known to exist. <a href=\"https:\/\/carleton.ca\/senate\/wp-content\/uploads\/Accommodation-for-Student-Activities-1.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">https:\/\/carleton.ca\/senate\/wp-content\/uploads\/Accommodation-for-Student-Activities-1.pdf<\/a><\/p>\n<p>For more information on academic accommodation, please contact the departmental administrator or visit: <a href=\"http:\/\/students.carleton.ca\/course-outline\" target=\"_blank\" rel=\"noopener noreferrer\">students.carleton.ca\/course-outline<\/a><\/p>\n<p><strong><span style=\"text-decoration: underline;\">Caveat<\/span><\/strong><br \/>\nObviously, I reserve the right to make adjustments or changes throughout the semester. Remember that you are responsible to learn about these changes, which will be posted on this website.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Syllabus Title Physical Chemistry II Course Description Further development of thermodynamic equations and their applications to mass changes, chemical potential, chemical equilibria, transport properties and advanced phase equilibria. Use of partial differentials and development of Maxwell&#8217;s relations will also be covered. Prerequisite CHEM 2103 or BIOC 2300 MATH 1005 or MATH 2007 Grading Scheme The [&hellip;]<\/p>\n","protected":false},"author":6,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_relevanssi_hide_post":"","_relevanssi_hide_content":"","_relevanssi_pin_for_all":"","_relevanssi_pin_keywords":"","_relevanssi_unpin_keywords":"","_relevanssi_related_keywords":"","_relevanssi_related_include_ids":"","_relevanssi_related_exclude_ids":"","_relevanssi_related_no_append":"","_relevanssi_related_not_related":"","_relevanssi_related_posts":"","_relevanssi_noindex_reason":"","_mi_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":"","_links_to":"","_links_to_target":""},"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v21.2 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Chem 2104 - The Barry Lab<\/title>\n<meta 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