Syllabus

Title

Inorganic Chemistry II

Course Description

Physical properties of coordination complexes, ligand substitutions and electron transfer reaction mechanisms, organometallic chemistry: bonding, nomenclature, and catalysis. The laboratory will introduce the student to a range of synthetic techniques and physical methods of characterization.

Prerequisite

CHEM 3503 (3507)

Preclusion

CHEM 3508 (3504)

Lectures

Wednesday, 8:35 – 11:25 am, Tory 208 (sync. on Brightspace)

Tutorial

Monday 10:35 – 11:25 am, Brightspace

Laboratory

The lab is run by Daniel Sun, and he has an extensive Brightspace site for it.

Exams

In-Term: Wednesday, March 2, 1.5 h, Brightspace
Final: TBD

Grading Scheme

CHEM 3504: the lab is 30% of your mark.

The other 70% is split up as follows:

  • Assignments 14%
  • In-term exam 21%
  • Final exam 35%

For CHEM 3508, there is no lab.

The course is split up as follows:

  • Assignments 20%
  • In-term exam 30%
  • Final exam 50%

Text

Gary L. Miessler, Paul J. Fischer, Donald A. Tarr, Inorganic Chemistry, 5th edition, Pearson, ISBN: 978-0321812001

COVID Accommodations

You may have already noticed the pandemic which is affecting our school year.

If you have an issue or need an accommodation, please ask. I won’t need a reason or documentation. I’d prefer to know ahead of time (with respect to deadlines and exams), but this isn’t always reasonable or possible.

Please just talk to me about what is going on, and together we will find a solution.

Topics

  1. Organometallic Chemistry
    • Nomenclature of organometallic complexes
    • Electron counting and the 18 and 16 electron rules
    • Special ligands: carbonyl, nitrosyl, hydride
    • Bonding to a metal via π-bonded electrons by ligands with extended π-systems
    • Carbene, and carbyne (alkylidyne) complexes
    • Characterization
  2. Reactions and Mechanism
    • Potential energy diagrams
    • Kinetic terms: Inert and labile complexes
    • Thermodynamic terms: Stable and unstable
    • Mechanisms and rate laws of ligand substitution: Dissociative, Associative and Interchange
    • Octahedral complexes showing Dissociative, Associative, and Conjugate Base mechanisms
    • Stereochemistry ligand substitution
    • Square planar complexes showing associative and dissociative mechanisms
    • The Trans effect
    • Electron transfer reactions: inner and outer sphere mechanism
  3. Organometallic Reactions and Mechanisms
    • Reactions involving gain or loss of ligands:
      Ligand dissociation and substitution, oxidative addition, reductive elimination, nucleophilic displacement
    • Reactions involving modification of ligands:
      Insertion, carbonyl insertion (alkyl migration), hydride elimination, abstraction
    • Organometallic catalytic processes:
      Deuteration, Hydroformylation, Monsanto acetic acid process, Wacker (Smidt) process, Hydrogenation by Wilkinson’s catalyst, Olefin metathesis, Ziegler-Natta polymerization, Water Gas reaction
  4. Parallels Between Main Group and Organometallic Chemistry
    • Survey of main group organometallic chemistry
    • π-bonding in Period 3 elements
    • Electron counting and Clusters and Zintl Ions
    • The isolobal analogy
    • Inert pair effect
    • 3c2e bonding and bridging
    • Hydrometallation
    • Displacement
    • Isoprene catalysis
    • The Friedl-Crafts reaction
    • Low valency in group 13

Survivors of Sexual Violence

As a community, Carleton University is committed to maintaining a positive learning, working and living environment where sexual violence will not be tolerated and is survivors are supported through academic accommodations as per Carleton’s Sexual Violence Policy. For more information about the services available at the university and to obtain information about sexual violence and/or support, visit: carleton.ca/sexual-violence-support

Requests for Academic Accommodation

You may need special arrangements to meet your academic obligations during the term. Please contact your instructor with any requests for academic accommodation (pregnancy, religion, disability, etc.) during the first two weeks of class, or as soon as possible after the need for accommodation is known to exist.

For an accommodation request, the processes can be found here:
carleton.ca/equity/wp-content/uploads/Student-Guide-to-Academic-Accommodation.pdf

Academic Accommodations for Students with Disabilities
If you have a documented disability requiring academic accommodations in this course, please contact the Paul Menton Centre for Students with Disabilities (PMC) at 613-520-6608 or pmc@carleton.ca for a formal evaluation or contact your PMC coordinator to send your instructor your Letter of Accommodation at the beginning of the term. You must also contact the PMC no later than two weeks before the first in-class scheduled test or exam requiring accommodation (if applicable). After requesting an accommodation from PMC, meet with your instructor as soon as possible to ensure accommodation arrangements are made. carleton.ca/pmc

Accommodation for Student Activities
Carleton University recognizes the substantial benefits, both to the individual student and for the university, that result from a student participating in activities beyond the classroom experience. Reasonable accommodation must be provided to students who compete or perform at the national or international level. Please contact your instructor with any requests for academic accommodation during the first two weeks of class, or as soon as possible after the need for accommodation is known to exist. https://carleton.ca/senate/wp-content/uploads/Accommodation-for-Student-Activities-1.pdf

For more information on academic accommodation, please contact the departmental administrator or visit: students.carleton.ca/course-outline

Caveat

Obviously, I reserve the right to make adjustments or changes throughout the semester. Remember that you are responsible to learn about these changes, which will be posted on this website.